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Low-temperature solid-oxide fuel cells utilizing thin bilayer electrolytes
Author(s): Tsai TP, Perry E, Barnett S
Source: JOURNAL OF THE ELECTROCHEMICAL SOCIETY    Volume: 144    Issue: 5    Pages: L130-L132    Published: MAY 1997  
Times Cited: 48     References: 21     
Abstract: Solid-oxide fuel cells (SOFCs) with electrolytes that provide high open-circuit voltage (OCV) and low ohmic loss down to 550 degrees C are described. The electrolytes were bilayers consisting of a 4 to 8 mu m thick Y-doped ceria (YDC) layer with a 1 to 1.5 mu m thick Y-doped zirconia (YSZ) layer on the fuel side. The cathode/supports were La0.95Sr0.15MnO3-YSZ. The anodes consisted of thin YDC and Ni-YSZ layers. The YDC/YSZ electrolyte SOFCs yielded 85 to 98% of the theoretical OCV, compared with approximate to 50% for YDC electrolyte SOFCs. The cathode overpotential, which was a main factor limiting SOFC power density, was lower for YDC/YSZ than YSZ electrolytes. The maximum power density at 600 degrees C, 210 mW/cm(2), is higher than for previously reported SOFCs.
Document Type: Article
Language: English
Reprint Address: Tsai, TP (reprint author), NORTHWESTERN UNIV, DEPT MAT SCI & ENGN, EVANSTON, IL 60208 USA
Publisher: ELECTROCHEMICAL SOC INC, 10 SOUTH MAIN STREET, PENNINGTON, NJ 08534
Subject Category: Electrochemistry; Materials Science, Coatings & Films
IDS Number: XD006
ISSN: 0013-4651
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